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3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride

  • Name 3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride
  • CAS 52314-67-7
  • Purity 99%
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Product Details

Cost-effective and customizable 3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride 52314-67-7 for sale

  • Molecular Formula: C8H9Cl3O
  • Molecular Weight: 227.518
  • Vapor Pressure: 0.0341mmHg at 25°C 
  • Refractive Index: 1.58 
  • Boiling Point: 242.4 °C at 760 mmHg 
  • Flash Point: 98.9 °C 
  • PSA: 17.07000 
  • Density: 1.424 g/cm3 
  • LogP: 3.34300 

3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride(Cas 52314-67-7) Usage

Flammability and Explosibility

Notclassified

Synthesis

3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride can be prepared by Permethric acid and catalyst stirred in toluene with phosgene at 80-90℃ for 1.5h.

InChI:InChI=1/C8H9Cl3O/c1-8(2)4(3-5(9)10)6(8)7(11)12/h3-4,6H,1-2H3

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52314-67-7 Process route

cis-permethrinic acid
59042-49-8

cis-permethrinic acid

(+/-)-cis-2-(2,2-dichloroethenyl)-3,3-dimethylcyclopropanecarboxylic acid chloride
52314-67-7,60254-21-9,61914-47-4,66182-41-0,66182-42-1,68539-75-3,69831-14-7,76984-70-8,77026-59-6

(+/-)-cis-2-(2,2-dichloroethenyl)-3,3-dimethylcyclopropanecarboxylic acid chloride

Conditions
Conditions Yield
With thionyl chloride; Heating;
With thionyl chloride; for 14h; Ambient temperature;
With thionyl chloride; N,N-dimethyl-formamide; In chloroform; at 40 ℃; for 3h;
With thionyl chloride; In dichloromethane; for 4h; Heating;
With thionyl chloride; Heating;
With thionyl chloride; In N,N-dimethyl-formamide; at 65 ℃; for 2h;
With thionyl chloride; at 50 ℃; for 4h;
With thionyl chloride; N,N-dimethyl-formamide; In chloroform; at 60 - 65 ℃; for 1h;
With thionyl chloride; at 65 ℃; for 1.5h;
With thionyl chloride;
cis,trans methyl 2,2-dimethyl-3-(2',2'-dichlorovinyl)-cyclopropanecarboxylate
61898-95-1

cis,trans methyl 2,2-dimethyl-3-(2',2'-dichlorovinyl)-cyclopropanecarboxylate

(+/-)-cis-2-(2,2-dichloroethenyl)-3,3-dimethylcyclopropanecarboxylic acid chloride
52314-67-7,60254-21-9,61914-47-4,66182-41-0,66182-42-1,68539-75-3,69831-14-7,76984-70-8,77026-59-6

(+/-)-cis-2-(2,2-dichloroethenyl)-3,3-dimethylcyclopropanecarboxylic acid chloride

Conditions
Conditions Yield
Multi-step reaction with 2 steps
1: NaOH / ethanol; H2 O / Heating
2: SOCl2 , DMF / CHCl3 / 3 h / 40 °C
With sodium hydroxide; thionyl chloride; N,N-dimethyl-formamide; In ethanol; chloroform; water;

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  • 79-37-8
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    oxalyl dichloride

  • 59609-49-3
    59609-49-3

    ethyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

52314-67-7 Downstream products

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    3-(2,2-Dichloro-vinyl)-2,2-dimethyl-cyclopropanecarboxylic acid dimethoxy-phosphorylmethyl ester

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    cypermethrine

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